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Simultaneous electrochemical sensing of hydroquinone and catechol using nanocomposite based on palygorskite and nitrogen doped graphene | |
Wu, Yuting1; Lei, Wu1; Xia, Mingzhu1; Wang, Fengyun1; Li, Caiwei1; Zhang, Cheng1; Hao, Qingli1; Zhang, Yuehua2 | |
2018-09-15 | |
发表期刊 | APPLIED CLAY SCIENCE |
ISSN | 0169-1317 |
EISSN | 1872-9053 |
卷号 | 162页码:38-45 |
摘要 | A novel electrochemical sensor based on nitrogen doped graphene (NGE) and palygorskite (Pal) for the simultaneous detection of hydroquinone (HQ) and catechol (CT) has been proposed. Pal is particularly pointed out for its appreciable specific surface area and reactive-OH groups on its surface. Acid treatment Pal demonstrated better physico-chemical properties, which are propitious to electrochemical sensor construction. The introduction of NGE not only improved the poor conductivity of Pal but also served as an excellent adherent matrix. The modified electrode demonstrated the enhanced redox peak currents of HQ and CT with good discrimination. Under optimized conditions, the linear ranges for HQ and CT were 2-50 mu M and 1-50 mu M, with detection limit (LOD) of 0.8 mu M and 0.13 mu M, respectively. The result designates that the Pal/NGE composite promises to be a new eco-friendly modified material for sensor fabrication. |
关键词 | Palygorskite Nitrogen doped graphene Hydroquinone Catechol Electrochemical sensor |
DOI | 10.1016/j.clay.2018.05.026 |
收录类别 | SCI |
语种 | 英语 |
WOS关键词 | CARBON-PASTE ELECTRODE ; GOLD NANOPARTICLES ; HYDROGEN-PEROXIDE ; ATTAPULGITE ; ADSORPTION ; SENSOR ; ACID ; ELECTROOXIDATION ; PERFORMANCE ; COMPOSITES |
WOS类目 | Chemistry, Physical ; Materials Science, Multidisciplinary ; Mineralogy |
WOS记录号 | WOS:000440775900005 |
出版者 | ELSEVIER SCIENCE BV |
国家 | 中国 |
省份 | Jiangsu |
项目编号 | 51472121 ; 51572127 ; 51572130 ; 51672134 ; 20133219110018 ; XNY-011 ; BK20160828 ; 1501016B ; NCET-12-0629 |
引用统计 | |
文献类型 | 期刊论文 |
专题 | 任务一_子任务一 循证社会科学证据集成 任务一 |
作者单位 | 1.Nanjing Univ Sci & Technol, Sch Chem Engn, Nanjing 210094, Jiangsu, Peoples R China; 2.Nantong Univ, Sch Chem & Chem Engn, Nantong 226019, Peoples R China |
推荐引用方式 GB/T 7714 | Wu, Yuting,Lei, Wu,Xia, Mingzhu,et al. Simultaneous electrochemical sensing of hydroquinone and catechol using nanocomposite based on palygorskite and nitrogen doped graphene[J]. APPLIED CLAY SCIENCE,2018,162:38-45. |
APA | Wu, Yuting.,Lei, Wu.,Xia, Mingzhu.,Wang, Fengyun.,Li, Caiwei.,...&Zhang, Yuehua.(2018).Simultaneous electrochemical sensing of hydroquinone and catechol using nanocomposite based on palygorskite and nitrogen doped graphene.APPLIED CLAY SCIENCE,162,38-45. |
MLA | Wu, Yuting,et al."Simultaneous electrochemical sensing of hydroquinone and catechol using nanocomposite based on palygorskite and nitrogen doped graphene".APPLIED CLAY SCIENCE 162(2018):38-45. |
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