Simultaneous electrochemical sensing of hydroquinone and catechol using nanocomposite based on palygorskite and nitrogen doped graphene
Wu, Yuting1; Lei, Wu1; Xia, Mingzhu1; Wang, Fengyun1; Li, Caiwei1; Zhang, Cheng1; Hao, Qingli1; Zhang, Yuehua2
2018-09-15
发表期刊APPLIED CLAY SCIENCE
ISSN0169-1317
EISSN1872-9053
卷号162页码:38-45
摘要A novel electrochemical sensor based on nitrogen doped graphene (NGE) and palygorskite (Pal) for the simultaneous detection of hydroquinone (HQ) and catechol (CT) has been proposed. Pal is particularly pointed out for its appreciable specific surface area and reactive-OH groups on its surface. Acid treatment Pal demonstrated better physico-chemical properties, which are propitious to electrochemical sensor construction. The introduction of NGE not only improved the poor conductivity of Pal but also served as an excellent adherent matrix. The modified electrode demonstrated the enhanced redox peak currents of HQ and CT with good discrimination. Under optimized conditions, the linear ranges for HQ and CT were 2-50 mu M and 1-50 mu M, with detection limit (LOD) of 0.8 mu M and 0.13 mu M, respectively. The result designates that the Pal/NGE composite promises to be a new eco-friendly modified material for sensor fabrication.
关键词Palygorskite Nitrogen doped graphene Hydroquinone Catechol Electrochemical sensor
DOI10.1016/j.clay.2018.05.026
收录类别SCI
语种英语
WOS关键词CARBON-PASTE ELECTRODE ; GOLD NANOPARTICLES ; HYDROGEN-PEROXIDE ; ATTAPULGITE ; ADSORPTION ; SENSOR ; ACID ; ELECTROOXIDATION ; PERFORMANCE ; COMPOSITES
WOS类目Chemistry, Physical ; Materials Science, Multidisciplinary ; Mineralogy
WOS记录号WOS:000440775900005
出版者ELSEVIER SCIENCE BV
国家中国
省份Jiangsu
项目编号51472121 ; 51572127 ; 51572130 ; 51672134 ; 20133219110018 ; XNY-011 ; BK20160828 ; 1501016B ; NCET-12-0629
引用统计
文献类型期刊论文
专题任务一_子任务一
循证社会科学证据集成
任务一
作者单位1.Nanjing Univ Sci & Technol, Sch Chem Engn, Nanjing 210094, Jiangsu, Peoples R China;
2.Nantong Univ, Sch Chem & Chem Engn, Nantong 226019, Peoples R China
推荐引用方式
GB/T 7714
Wu, Yuting,Lei, Wu,Xia, Mingzhu,et al. Simultaneous electrochemical sensing of hydroquinone and catechol using nanocomposite based on palygorskite and nitrogen doped graphene[J]. APPLIED CLAY SCIENCE,2018,162:38-45.
APA Wu, Yuting.,Lei, Wu.,Xia, Mingzhu.,Wang, Fengyun.,Li, Caiwei.,...&Zhang, Yuehua.(2018).Simultaneous electrochemical sensing of hydroquinone and catechol using nanocomposite based on palygorskite and nitrogen doped graphene.APPLIED CLAY SCIENCE,162,38-45.
MLA Wu, Yuting,et al."Simultaneous electrochemical sensing of hydroquinone and catechol using nanocomposite based on palygorskite and nitrogen doped graphene".APPLIED CLAY SCIENCE 162(2018):38-45.
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